Miras, H.N. , Ochoa, M.N.C., Long, D.L. and Cronin, L. (2010) Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}. Chemical Communications, 46(43), pp. 8148-8150. (doi: 10.1039/C0CC02849E)
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Publisher's URL: http://dx.doi.org/10.1039/C0CC02849E
Abstract
The reaction of molybdate with vanadium(V) in the presence of sulfite anions is explored showing how, via cation control, stepwise assembly through the {Mo11V7} cluster yields a {M25} cluster-based compound, [MoVI11VV5VIV2O52(μ9-SO3)(MoVI6VVO22)]10− (1a), which was first discovered using cryospray mass spectrometry, whereas switching the cation away from ammonium allows the direct formation of the spherical ‘Keplerate’ {Mo72V30} cluster.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Miras, H.N., Ochoa, M.N.C., Long, D.L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Journal Abbr.: | Chem. Comm. |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 08 October 2010 |
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