Synthesis of functionalized Morita–Baylis–Hillman adducts by a conjugate addition–elimination sequence

Aouzal, R. and Prunet, J. (2009) Synthesis of functionalized Morita–Baylis–Hillman adducts by a conjugate addition–elimination sequence. Organic and Biomolecular Chemistry, 7(17), pp. 3594-3598. (doi:10.1039/B907373F)

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Abstract

We have developed a new conjugate addition–elimination sequence for the diastereoselective synthesis of protected allylic syn 1,3-diols which are Morita–Baylis–Hillman adducts. The synthesis of the substrates involves a challenging cross-metathesis reaction that leads to hindered trisubstituted olefins.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Prunet, Dr Joelle
Authors: Aouzal, R., and Prunet, J.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Organic and Biomolecular Chemistry
Journal Abbr.:Org. Biomol. Chem.
ISSN:1477-0520
ISSN (Online):1477-0539

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