Long, D.-L. , Kögerler, P., Farrugia, L. and Cronin, L. (2003) Restraining symmetry in the formation of small polyoxomolybdates: building blocks of unprecedented topology resulting from "shrink-wrapping" [H2Mo16O52]10--type clusters. Angewandte Chemie (International Edition), 42(35), pp. 4180-4183. (doi: 10.1002/anie.200351615)
Full text not currently available from Enlighten.
Publisher's URL: http://dx.doi.org/10.1002/anie.200351615
Abstract
A mixed-valence polyoxomolybdate cluster [H2MoVI12MoV4O52]10− was isolated by a new “shrink-wrapping” approach to trap clusters that display low symmetry and nonspherical topology (see scheme; HMTAH=protonated hexamethylenetetraamine). The unprecedented cluster topology results from the restriction of the reorganization of the cluster framework to more symmetrical clusters, yet it reacts with electrophiles, such as FeII.
Item Type: | Articles |
---|---|
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Farrugia, Dr Louis and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Long, D.-L., Kögerler, P., Farrugia, L., and Cronin, L. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry University Centres > Glasgow Materials Research Initiative |
Journal Name: | Angewandte Chemie (International Edition) |
Journal Abbr.: | Angew Chem Int Ed Engl |
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
ISSN: | 1433-7851 |
ISSN (Online): | 1521-3773 |
University Staff: Request a correction | Enlighten Editors: Update this record