Fielden, J., Long, D.-L. and Cronin, L. (2004) Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes. Chemical Communications(19), pp. 2156-2157. (doi: 10.1039/b407229d)
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Publisher's URL: http://dx.doi.org/10.1039/b407229d
Abstract
Reversible geometry reorganisations are demonstrated by <i>cis</i>-3,5-diamino-trans-hydroxycyclohexane (<i>cis</i>,<i>trans</i>-DAHC) copper(II) fluoride complexes, with the concentration of water in the mother liquor controlling interconversion between blue crystals of 5-coordinate <i>syn</i>-[Cu(DAHC)<sub>2</sub>F](F)·2CH<sub>3</sub>OH·H<sub>2</sub>O and red crystals of 4-coordinate <i>anti</i>-[Cu(DAHC)<sub>2</sub>](F)<sub>2</sub>·2H<sub>2</sub>O. Reversible geometry reorganisations are demonstrated by cis-3,5-diamino-trans-hydroxycyclohexane (cis,trans-DAHC) copper(II) fluoride complexes. The concentration of water in the mother liquor allows the interconversion of blue crystals of <b>1</b> to red crystals of <b>2</b><i>via</i> subtle changes in the solvent and secondary coordination sphere.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Long, Dr Deliang and Fielden, Dr John and Cronin, Professor Lee |
| Authors: | Fielden, J., Long, D.-L., and Cronin, L. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry University Centres > Glasgow Materials Research Initiative |
| Journal Name: | Chemical Communications |
| ISSN: | 1359-7345 |
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