Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species

Ritchie, C., Burkholder, E., Kögerler, P. and Cronin, . (2006) Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species. Dalton Transactions, pp. 1712-1714. (doi:10.1039/b518316b)

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Publisher's URL: http://dx.doi.org/10.1039/b518316b

Abstract

Unsymmetrical functionalization of a discrete α-{SiW<sub>12</sub>O<sub>40</sub>} Keggin with two heterometallic building blocks, a Cu(II) dimer and a Cu(II) monomer, results in the formation of [{Cu<sub>2</sub>(O<sub>2</sub>CMe)<sub>2</sub>(5,5'-dimethyl-2,2'-bipy)<sub>2</sub>}{Cu(5,5'-dimethyl-2,2' -bipy)<sub>2</sub>}SiW<sub>12</sub>O<sub>40</sub>]that displays interesting physical properties.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Ritchie, Mr Christopher and Burkholder, Dr Eric and Cronin, Professor Lee
Authors: Ritchie, C., Burkholder, E., Kögerler, P., and Cronin, .
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
University Centres > Glasgow Materials Research Initiative
Journal Name:Dalton Transactions
ISSN:1477-9226

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