Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks

Streb, C., Long, D.-L. and Cronin, L. (2006) Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks. CrystEngComm, 8, pp. 629-634. (doi:10.1039/b605285a)

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Publisher's URL: http://dx.doi.org/10.1039/b605285a

Abstract

The synthesis and structural characterization of three new polyoxomolybdenum(V) phosphate frameworks have been achieved by using dimeric {Mo6}2 moieties as inorganic building blocks and protonated organic amines as counter ions. The structure-directing role of the organic cations was investigated and it was shown, that the geometry and the rigidity of the amines as well as their hydrogen bonding capabilities influence the formation of layered or chain-like superstructures.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten
Authors: Streb, C., Long, D.-L., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
University Centres > Glasgow Materials Research Initiative
Journal Name:CrystEngComm
ISSN:1466-8033

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