Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry

Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi:10.1002/anie.200806343)

Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi:10.1002/anie.200806343)

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Abstract

The cryo game: Heteroatom-embedded nanofunctional clusters are described that incorporate a [TeVIO6]6- species contained within a {W18O54} cage. Not only does the tellurium-based species activate the {W18O54} cluster surface for assembly of larger nanoscale structures, such as [H10TeVI2W58O198]26-, it also undergoes a redox transformation inside the cluster from [TeVIO6]6- to [TeIVO3]2-.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr De Liang and Cronin, Professor Leroy
Authors: Yan, J., Long, D.-L., Wilson, E.F., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew Chem Int Ed Engl
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:01 January 2009

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