Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi: 10.1002/anie.200806343)
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Abstract
The cryo game: Heteroatom-embedded nanofunctional clusters are described that incorporate a [TeVIO6]6- species contained within a {W18O54} cage. Not only does the tellurium-based species activate the {W18O54} cluster surface for assembly of larger nanoscale structures, such as [H10TeVI2W58O198]26-, it also undergoes a redox transformation inside the cluster from [TeVIO6]6- to [TeIVO3]2-.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Yan, J., Long, D.-L., Wilson, E.F., and Cronin, L. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Angewandte Chemie (International Edition) |
| Journal Abbr.: | Angew Chem Int Ed Engl |
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
| ISSN: | 1433-7851 |
| ISSN (Online): | 1521-3773 |
| Published Online: | 01 January 2009 |
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