Heteroatom-controlled kinetics of switchable polyoxometalate frameworks

Thiel, J., Ritchie, C., Streb, C., Long, D. L. and Cronin, L. (2009) Heteroatom-controlled kinetics of switchable polyoxometalate frameworks. Journal of the American Chemical Society, 131(12), pp. 4180-4181. (doi:10.1021/ja809422k)

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Publisher's URL: http://dx.doi.org/10.1021/ja809422k

Abstract

The framework materials [(W72Mn12O268X7)-O-II/III](52-/40-) undergo heteroatom (X)-controlled reversible SC-SC redox reactions whereby the Ge-templated framework reduction is fast and reoxidation is slow. The opposite trend is set for the Si-templated framework, and these processes can be followed optically, spectroscopically and crystallographically.

Item Type:Articles
Keywords:CATALYSIS COPPER(II) framework materials Frameworks KINETICS POLYOXOMETALATE REDOX REDUCTION
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten
Authors: Thiel, J., Ritchie, C., Streb, C., Long, D. L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of the American Chemical Society
Publisher:American Chemical Society
ISSN:0002-7863
ISSN (Online):1520-5126
Published Online:10 March 2009

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
457781Consortium of excellence in advanced sensors and their application.Leroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/F012519/1Chemistry