Thiel, J., Ritchie, C., Streb, C., Long, D. L. and Cronin, L. (2009) Heteroatom-controlled kinetics of switchable polyoxometalate frameworks. Journal of the American Chemical Society, 131(12), pp. 4180-4181. (doi: 10.1021/ja809422k)
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Publisher's URL: http://dx.doi.org/10.1021/ja809422k
Abstract
The framework materials [(W72Mn12O268X7)-O-II/III](52-/40-) undergo heteroatom (X)-controlled reversible SC-SC redox reactions whereby the Ge-templated framework reduction is fast and reoxidation is slow. The opposite trend is set for the Si-templated framework, and these processes can be followed optically, spectroscopically and crystallographically.
Item Type: | Articles |
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Keywords: | CATALYSIS COPPER(II) framework materials Frameworks KINETICS POLYOXOMETALATE REDOX REDUCTION |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten |
Authors: | Thiel, J., Ritchie, C., Streb, C., Long, D. L., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of the American Chemical Society |
Publisher: | American Chemical Society |
ISSN: | 0002-7863 |
ISSN (Online): | 1520-5126 |
Published Online: | 10 March 2009 |
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