Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry

Song, Y. -F., Long, D. L. , Kelly, S. E. and Cronin, L. (2008) Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry. Inorganic Chemistry, 47(20), pp. 9137-9139. (doi:10.1021/ic801366r)

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Abstract

The unsymmetrical Mn-Anderson polyoxometalate cluster, [N(C4H9)(4)](3)[MnMo6O18(C4H6O3NO2)(C4H6O3NH2)] (1; N(C4H9)(4)(+) = TBA(+)), has been prepared and characterized by X-ray crystallography and electrospray ionization mass spectrometry (ESI-MS). Covalent functionalization of compound 1 leads to the controlled assemblies of unsymmetrical alkoxopolyoxometalate clusters of compounds 2-5, which can be directly observed in solution as revealed by ESI-MS studies.

Item Type:Articles
Keywords:ASSEMBLIES BUILDING-BLOCKS CLUSTER CLUSTERS CRYSTALLOGRAPHY FUNCTIONALIZATION HETEROPOLYMOLYBDATES LIGANDS mass spectrometry MASS-SPECTROMETRY NANOSTRUCTURES organic-inorganic hybrids POLYOXOMETALATE POLYOXOMETALATE CLUSTERS POLYOXOMOLYBDATES STRUCTURAL CHARACTERIZATION X-RAY X-Ray Crystallography
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Song, Dr Yufei and Long, Dr Deliang and Cronin, Professor Lee
Authors: Song, Y. -F., Long, D. L., Kelly, S. E., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
ISSN:0020-1669

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