Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

Shiga, T., Newton, G. N., Mathieson, J. S., Tetsuka, T., Nihei, M., Cronin, L. and Oshio, H. (2010) Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages. Dalton Transactions, 39(20), pp. 4730-4733. (doi:10.1039/b925399h)

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Abstract

Enantiomeric, ferromagnetically coupled decanuclear {Ni6Fe4} cages with adamantane-like cores were synthesized around templating tetraethylammonium cations, as shown by crystallographic analysis and CSI-MS, and their homochiral nature was confirmed by circular dichroism measurements.

Item Type:Articles
Keywords:ASSEMBLIES BEHAVIOR CAGE CATALYSIS CIRCULAR-DICHROISM CLUSTERS COMPLEX FERRIMAGNET LINKAGE ISOMERISM MAGNETIC-PROPERTIES MOLECULE SQUARE
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Cronin, Professor Lee
Authors: Shiga, T., Newton, G. N., Mathieson, J. S., Tetsuka, T., Nihei, M., Cronin, L., and Oshio, H.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
ISSN:1477-9226

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