Reversible redox reactions in an extended polyoxometalate framework solid

Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N. , Long, D.L. , Boyd, T., Peacock, R.D., McGlone, T. and Cronin, L. (2008) Reversible redox reactions in an extended polyoxometalate framework solid. Angewandte Chemie (International Edition), 47(36), pp. 6881-6884. (doi:10.1002/anie.200802594)

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Abstract

Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent. Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.

Item Type:Articles
Keywords:cluster compounds CLUSTERS framework materials HYBRID LIGANDS METAL OXIDATION POLYOXOMETALATE polyoxometalates REDOX redox chemistry self-assembly TOPOLOGY.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Peacock, Dr Robert and Moiras, Dr Haralampos and Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten
Authors: Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N., Long, D.L., Boyd, T., Peacock, R.D., McGlone, T., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew. Chem. Int. Ed. Engl.
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:31 July 2008

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