A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)(2)Co2Na2(H2O)(2)](18-)

Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L. , Xu, L. and Cronin, L. (2009) A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)(2)Co2Na2(H2O)(2)](18-). Dalton Transactions(33), pp. 6483-6486. (doi:10.1039/b907410d)

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Abstract

Using multifunctional organocations a novel heteropolyanion, [(P4W6O34)(2)Co2Na2(H2O)(2)](18-), with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.

Item Type:Articles
Keywords:BUILDING-BLOCKS CELTIC-RING ISOPOLYOXOTUNGSTATE CHEMISTRY CLUSTER CLUSTER CAGE CLUSTERS COMPLEXES FEATURES GROWTH HYBRID KEGGIN POLYOXOMETALATE MOLECULE MOLECULES POLYOXOMETALATE STRUCTURAL FEATURES
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr De Liang and Cronin, Professor Leroy
Authors: Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L., Xu, L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
ISSN:1477-9226

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
456571Directly reconfigurable nanomachinesLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/F009410/1Chemistry