cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe-III and Pd-II coordination clusters

Newton, G. N., Cooper, G. J. T. , Schuch, D., Shiga, T., Khanra, S., Long, D. L. , Oshio, H. and Cronin, L. (2009) cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe-III and Pd-II coordination clusters. Dalton Transactions(9), pp. 1549-1553. (doi:10.1039/b815200d)

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Abstract

A dodecanuclear Fe-III complex, consisting of two {Fe-6} units coupled across a single hydroxy-bridge and a cage-like Pd-II trimer were synthesised using the highly branched, pentadecadentate chelating ligand cis,cis-1,3,5-cyclohexanetriamine-N,N,N',N',N '',N ''-hexaacetic acid(H(6)hact).

Item Type:Articles
Keywords:BUILDING-BLOCKS CHEMISTRY CIS,TRANS-1,3,5-TRIAMINOCYCLOHEXANE CLUSTER CLUSTERS COMPLEX COMPLEXES COORDINATION COORDINATION CLUSTERS CORES LIGAND LIGANDS SINGLE SINGLE-MOLECULE MAGNETS TETRANUCLEAR UNIT UNITS
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Khanra, Dr Sumit and Long, Dr Deliang and Cooper, Dr Geoff and Cronin, Professor Lee
Authors: Newton, G. N., Cooper, G. J. T., Schuch, D., Shiga, T., Khanra, S., Long, D. L., Oshio, H., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
ISSN:1477-9226

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