Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters

Newton, G.N., Cooper, G.J.T. , Kogerler, P., Long, D.L. and Cronin, L. (2008) Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters. Journal of the American Chemical Society, 130(3), pp. 790-791. (doi:10.1021/ja0768183)

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Abstract

'Nuclearity switching' from a {Co-13} supercluster to a {Co-12} species via the addition of Co-3(2-) anions is reported and can be traced in solution using electrospray MS techniques. In addition, cryospray MS can be used to identify the entire cluster in solution despite the relative lability of its constituents.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr De Liang and Cooper, Dr Geoffrey and Cronin, Professor Leroy
Authors: Newton, G.N., Cooper, G.J.T., Kogerler, P., Long, D.L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of the American Chemical Society
ISSN:0002-7863

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
406941Realising the concept of the artificial chemical cell using vesiclesLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/D022304/1Chemistry