Murrie, M. (2010) Cobalt(II) single-molecule magnets. Chemical Society Reviews, 39(6), pp. 1986-1995. (doi: 10.1039/b913279c Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland.)
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Abstract
This short tutorial review covers recent progress in the field of polynuclear cobalt(II)-based complexes, which display slow magnetic relaxation at low temperature. Cobalt(II) single-molecule magnets (SMMs) can display much larger magnetic anisotropies and hence, potentially higher blocking temperatures than SMMs based on ions where the zero-field splitting originates from a second order spin-orbit coupling, such as manganese(III).
Item Type: | Articles |
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Keywords: | Anisotropy, anisotropy barrier cage, chemistry, clusters, co complexes, high-spin molecules, ions, low-temperature magnetization, recent progress smm behavior, symmetry. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Murrie, Professor Mark |
Authors: | Murrie, M. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Society Reviews |
ISSN: | 0306-0012 |
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