Montgomery, C. P., New, E. J., Parker, D. and Peacock, R. D. (2008) Enantioselective regulation of a metal complex in reversible binding to serum albumin: dynamic helicity inversion signalled by circularly polarised luminescence. Chemical Communications(36), pp. 4261-4263. (doi: 10.1039/b810978h)
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Abstract
The helicity of the (SSS)-Delta enantiomer of a terbium and europium(III) complex is inverted on reversible binding to 'drug site II' of serum albumin, signalled by a switch in its circularly polarised emission; no such behaviour occurs with the (RRR)-Lambda complexes, thereby defining a unique chiroptical probe of albumin binding.
| Item Type: | Articles |
|---|---|
| Keywords: | BINDING Chirality COBALT(II) COMPLEX COMPLEX COMPLEXES DICHROISM ENANTIOPURE LANTHANIDE TETRAAMIDE COMPLEXES Luminescence METAL-COMPLEXES NMR RECOGNITION REVERSIBLE BINDING SERA SPECTROSCOPY STATE SWITCH Z-DNA |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Peacock, Dr Robert |
| Authors: | Montgomery, C. P., New, E. J., Parker, D., and Peacock, R. D. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| ISSN: | 1359-7345 |
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