Polymerisation of a Cu(II) dimer into 1D chains using high pressure

Moggach, S.A., Galloway, K.W., Lennie, A.R., Parois, P., Rowantree, N., Brechin, E.K., Warren, J.E., Murrie, M. and Parsons, S. (2009) Polymerisation of a Cu(II) dimer into 1D chains using high pressure. CrystEngComm, 11(12), pp. 2601-2604. (doi: 10.1039/b912707k)

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Abstract

Long intermolecular interactions are converted into covalent bonds when the complex [Cu-2(OH)(citrate)(Guanidine)2](-) is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Murrie, Professor Mark
Authors: Moggach, S.A., Galloway, K.W., Lennie, A.R., Parois, P., Rowantree, N., Brechin, E.K., Warren, J.E., Murrie, M., and Parsons, S.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:CrystEngComm
ISSN:1466-8033

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