Moggach, S.A., Galloway, K.W., Lennie, A.R., Parois, P., Rowantree, N., Brechin, E.K., Warren, J.E., Murrie, M. and Parsons, S. (2009) Polymerisation of a Cu(II) dimer into 1D chains using high pressure. CrystEngComm, 11(12), pp. 2601-2604. (doi: 10.1039/b912707k)
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Abstract
Long intermolecular interactions are converted into covalent bonds when the complex [Cu-2(OH)(citrate)(Guanidine)2](-) is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Murrie, Professor Mark |
Authors: | Moggach, S.A., Galloway, K.W., Lennie, A.R., Parois, P., Rowantree, N., Brechin, E.K., Warren, J.E., Murrie, M., and Parsons, S. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | CrystEngComm |
ISSN: | 1466-8033 |
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