Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control

Mitchell, S. G., Ritchie, C., Long, D.L. and Cronin, L. (2008) Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control. Dalton Transactions(11), pp. 1415-1417. (doi:10.1039/b715885h)

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Abstract

Three discrete cobalt-substituted silicotungstates, [Co-3(H2O)(B-beta-SiW9O34)(B-beta-SiW8O29(OH)(2))](12-) (1), [Co-3(H2O)(B-alpha-SiW9O34)(B-beta-SiW8O31)](14-) (2), and [Co9Cl2(OH)(3)(H2O)(9)(B-beta-SiW8O31)(3)](17-) (3), have been synthesized using a synthetic approach involving Co(II) ions, the dilacunary [gamma-SiW10O36](8-) polyanion and a bulky organic cation in basic media; all three compounds have been fully characterized and their position as structural intermediates in Co-containing silicotungstate chemistry is described.

Item Type:Articles
Keywords:ACHIEVEMENTS CATION CHEMISTRY CLUSTERS HETEROPOLYANIONS INTERMEDIATE ION IONS METAL POLYOXOMETALATE TRANSITION
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr De Liang and Cronin, Professor Leroy
Authors: Mitchell, S. G., Ritchie, C., Long, D.L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
ISSN:1477-9226

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