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Controlling nucleation of the cyclic heteropolyanion {P8W48}: a cobalt-substituted phosphotungstate chain and network

Mitchell, S. G., Gabb, D., Ritchie, C., Hazel, N., Long, D. L., and Cronin, L. (2009) Controlling nucleation of the cyclic heteropolyanion {P8W48}: a cobalt-substituted phosphotungstate chain and network. CrystEngComm, 11 (1). pp. 36-39. ISSN 1466-8033 (doi:10.1039/b813066c)

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Abstract

Two cyclic cobalt-substituted heteropolyoxometalates K15Li5[Co-10(H2O)(34)(P8W48O184)]center dot 54H(2)O (1) and K8Li12[Co-10 (H2O)(44)(P8W48O184)]center dot 60H(2)O (2) have been synthesised from the reaction of Co(II) ions and the superlacunary {P8W48} polyanion in mildly acidic aqueous media. The cluster's anion cavities are filled with Co(II) and K cations and careful manipulation of reaction conditions determines the formation of distinct Co-linked frameworks.

Item Type:Article
Status:Published
Refereed:Yes
Glasgow Author(s):Long, Dr De Liang and Cronin, Prof Leroy
Authors: Mitchell, S. G., Gabb, D., Ritchie, C., Hazel, N., Long, D. L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:CrystEngComm
ISSN:1466-8033

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