Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties

Miras, H.N. , Long, D.L. , Kogerler, P. and Cronin, L. (2008) Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties. Dalton Transactions(2), pp. 214-221. (doi:10.1039/b714285d)

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Abstract

A family of polyoxometalates with the composition [H2V3M17O62](6-) features a Dawson-like architecture containing two tetrahedral {(VO4)-O-V} templates rather than main group hetero-anions ({PO4} or {SO4} etc.) typically associated with classical heteropolyacids, situated within a mixed-metal {(M17VO54)-V-VI-O-IV} cage and these clusters were first discovered using mass spectrometry.

Item Type:Articles
Keywords:BUILDING-BLOCKS CAGE CAGES CHEMISTRY CLUSTER CLUSTERS DAWSON ANIONS DISCOVERY DOT-S INTERACTIONS FAMILY FEATURES HETEROPOLYACIDS ISOMER mass spectrometry MASS-SPECTROMETRY ONE-ELECTRON OXIDATION POLYOXOMETALATE POLYOXOMETALATE CHEMISTRY polyoxometalates REDUCTION SOLID-STATE STATE SUBSTITUTED HETEROPOLYANIONS SYMMETRY TEMPLATE
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Dr Haralampos and Long, Dr Deliang and Cronin, Professor Lee
Authors: Miras, H.N., Long, D.L., Kogerler, P., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Publisher:Royal Society of Chemistry
ISSN:1477-9226
ISSN (Online):1477-9234
Published Online:02 November 2007

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