Long, D.L. , Streb, C., Song, Y.-F., Mitchell, S. and Cronin, L. (2008) Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion. Journal of the American Chemical Society, 130(6), 1830-+. (doi: 10.1021/ja075940z)
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Abstract
A route to unravel and the complexities of polyoxometalates in solution using electrospray mass spectrometry is presented. This reveals the limited speciation of the clusters in organic solvent compared to that in aqueous solution and allows the unambiguous assignment of the protonation states of the cluster as a function of heteroatom inclusion.
| Item Type: | Articles |
|---|---|
| Keywords: | AQUEOUS-SOLUTION CLUSTER CLUSTERS COMPLEXITIES DAWSON DERIVATIVES IONS ISOPOLYOXOTUNGSTATE mass spectrometry MASS-SPECTROMETRY POLYOXOMETALATE polyoxometalates POLYOXOTUNGSTATE ROUTE SOLVENT STATE TUNGSTOPHOSPHATE |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Song, Dr Yufei and Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten |
| Authors: | Long, D.L., Streb, C., Song, Y.-F., Mitchell, S., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of the American Chemical Society |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| ISSN (Online): | 1520-5126 |
| Published Online: | 18 January 2008 |
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