Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion

Long, D.L. , Streb, C., Song, Y.-F., Mitchell, S. and Cronin, L. (2008) Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion. Journal of the American Chemical Society, 130(6), 1830-+. (doi:10.1021/ja075940z)

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Abstract

A route to unravel and the complexities of polyoxometalates in solution using electrospray mass spectrometry is presented. This reveals the limited speciation of the clusters in organic solvent compared to that in aqueous solution and allows the unambiguous assignment of the protonation states of the cluster as a function of heteroatom inclusion.

Item Type:Articles
Keywords:AQUEOUS-SOLUTION CLUSTER CLUSTERS COMPLEXITIES DAWSON DERIVATIVES IONS ISOPOLYOXOTUNGSTATE mass spectrometry MASS-SPECTROMETRY POLYOXOMETALATE polyoxometalates POLYOXOTUNGSTATE ROUTE SOLVENT STATE TUNGSTOPHOSPHATE
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Song, Dr Yufei and Long, Dr De Liang and Cronin, Professor Leroy and Streb, Mr Carsten
Authors: Long, D.L., Streb, C., Song, Y.-F., Mitchell, S., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of the American Chemical Society
Publisher:American Chemical Society
ISSN:0002-7863
ISSN (Online):1520-5126
Published Online:18 January 2008

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
400012Understanding and controlling the self assembly of nanoscale polyoxometalate clustersLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/C542827/1Chemistry