Capture of periodate in a {W18O54} cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)](6-) embedded with high-valent iodine

Long, D.L. , Song, Y.-F., Wilson, E.F., Kogerler, P., Guo, S.X., Bond, A.M., Hargreaves, J.S.J. and Cronin, L. (2008) Capture of periodate in a {W18O54} cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)](6-) embedded with high-valent iodine. Angewandte Chemie (International Edition), 47(23), pp. 4384-4387. (doi:10.1002/anie.200800041)

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Item Type:Articles
Keywords:CAGE CAPTURE CHEMISTRY CLUSTER CLUSTER CAGE Dawson clusters electronic structure Frameworks HYBRID mass spectrometry MOLECULES POLYOXOMETALATE polyoxometalates SYMMETRY tungsten.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Hargreaves, Professor Justin and Long, Dr Deliang and Cronin, Professor Lee and Song, Dr Yufei
Authors: Long, D.L., Song, Y.-F., Wilson, E.F., Kogerler, P., Guo, S.X., Bond, A.M., Hargreaves, J.S.J., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew Chem Int Ed Engl
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3773

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
377311Trapping fundamentally new types of polyoxometalate cluster using a shrink wrapping approachLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)GR/T17205/01Chemistry