A new C-C bond forming annulation reaction leading to pH switchable heterocycles

Kitson, P. J., Parenty, A. D. C., Richmond, C. J., Long, D. L. and Cronin, L. (2009) A new C-C bond forming annulation reaction leading to pH switchable heterocycles. Chemical Communications(27), pp. 4067-4069. (doi:10.1039/b905383b)

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Publisher's URL: http://dx.doi.org/10.1039/b905383b

Abstract

A C-C bond forming reaction resulting from the alpha-addition of carbon based nucleophiles to N-bromoethyl phenanthridinium leads to the formation of 2,3-dihydro-12H-pyrrolo[1,2-f] phenanthridine-based derivatives which undergo reversible ring-opening/closing under pH control.

Item Type:Articles
Keywords:BINDING BOND CARBON COMPONENTS CYCLIZATION DERIVATIVES LIGHT-DRIVEN LOGIC MACHINE MOLECULAR ELECTRONICS ONE-POT PH ROTAXANE SYSTEMS
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Kitson, Dr Philip and Parenty, Mr Alexis and Richmond, Mr Craig and Long, Dr De Liang and Cronin, Professor Leroy
Authors: Kitson, P. J., Parenty, A. D. C., Richmond, C. J., Long, D. L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
Published Online:28 May 2009

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
400012Understanding and controlling the self assembly of nanoscale polyoxometalate clustersLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/C542827/1Chemistry