'Lock and key' control of optical properties in a push-pull system

Jordan, B.J. et al. (2008) 'Lock and key' control of optical properties in a push-pull system. Chemical Communications(14), pp. 1653-1655. (doi:10.1039/b718015b)

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Abstract

We report the modulation of the absorbance of a flavin push - pull derivative through specific recognition by a complementary diamidopyridine (DAP), shifting the flavin intramolecular charge transfer band by similar to 30 nm.

Item Type:Articles
Keywords:AZOBENZENE CHARGE-TRANSFER DONOR-ACCEPTOR DYES FLAVOENZYME ACTIVITY HYPERPOLARIZABILITY METHYL RED MODEL SYSTEMS MODULATION molecular recognition OPTICAL-PROPERTIES RECOGNITION STRUCTURAL CHARACTERISTICS SYSTEM
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Caldwell, Dr Stuart and Cooke, Professor Graeme and Rabani, Dr Gouher
Authors: Jordan, B.J., Pollier, M.A., Ofir, Y., Joubanian, S., Mehtala, J.G., Sinkel, C., Caldwell, S.T., Kennedy, A., Rabani, G., Cooke, G., and Rotello, V.M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Journal Abbr.:Chem. Comm.
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:01 February 2008

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
425091Towards electrochemically controlled 'smart' macromoleculesGraeme CookeEngineering & Physical Sciences Research Council (EPSRC)EP/C53056X/2CHEM - CHEMISTRY