Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo-176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)(80)]Cl-27 center dot 450H(2)O

Imai, H., Akutagawa, T., Kudo, F., Ito, M., Toyoda, K., Noro, S., Cronin, L. and Nakamura, T. (2009) Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo-176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)(80)]Cl-27 center dot 450H(2)O. Journal of the American Chemical Society, 131(38), 13578-+. (doi:10.1021/ja9048042)

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Abstract

Single crystals of the nanoscale polyoxomolybdate wheel, Na15Fe3Co16[Mo176O528(H2O)(80)]Cl-27 center dot 450H(2)O, was synthesized by the condensation reaction of Na0.4Co0.8[MoO4]center dot 1.5H(2)O at low pH and in the presence of an iron-based reducing agent, and these crystals were characterized by the synchrotron-based X-ray single crystal analysis, magnetic susceptibility, and ionic conductivity measurements.

Item Type:Articles
Keywords:ASSEMBLIES CONDENSATION CONDUCTIVITY CRYSTAL PH SINGLE X-RAY
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Cronin, Professor Leroy
Authors: Imai, H., Akutagawa, T., Kudo, F., Ito, M., Toyoda, K., Noro, S., Cronin, L., and Nakamura, T.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of the American Chemical Society
ISSN:0002-7863

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