Stereoselective synthesis of alicylic amines

Graham, K.F., Hindle, K.T., Jackson, S.D. , Williams, D.J.M. and Wuttke, S. (2010) Stereoselective synthesis of alicylic amines. Topics in Catalysis, 53(15-18), pp. 1121-1125. (doi:10.1007/s11244-010-9544-2)

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Abstract

The hydrogenation 4-alkylanilines over Rh/silica catalysts display an antipathetic particle size effect suggesting that the active site is a terrace face. The effect of the solvent on product cis:trans ratio was related to polar solvents stabilising an imine intermediate. The products inhibited the reaction due to their increased basicity which allowed a strong metal-nitrogen interaction.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Jackson, Professor Samuel
Authors: Graham, K.F., Hindle, K.T., Jackson, S.D., Williams, D.J.M., and Wuttke, S.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Topics in Catalysis
ISSN:1022-5528

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