Ferguson, A., McGregor, J., Brechin, E.K., Thomas, L.H. and Murrie, M. (2009) Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters. Dalton Transactions(43), pp. 9395-9397. (doi: 10.1039/b913102g)
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Abstract
The synthesis, structure and magnetic properties of [Fe14O4(OH)(4)(H2L)(2)(HL)(4)(piv)(20)] (1) and [Fe8Cu2O4(H2L)(4)-(HL)(2)(OBz)(12)] (2) are reported (H3L = 2-amino-2-(hydroxymethyl) propane-1,3-diol): both complexes have unique core structures and display non-zero spin ground states.
Item Type: | Articles |
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Keywords: | Bis-tris cluster, clusters, complex, complexes, core crystal-structure ,ground-state hysteresis, iron(iii), magnetic-properties, MN pivalate ,single-molecule-magnet, state symmetry. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Thomas, Dr Lynne and Murrie, Professor Mark |
Authors: | Ferguson, A., McGregor, J., Brechin, E.K., Thomas, L.H., and Murrie, M. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Dalton Transactions |
ISSN: | 1477-9226 |
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