An investigation of the complexation of a TTF derivative with alpha-, beta- and gamma-cyclodextrins in aqueous media

Bria, M., Cooke, G. , Cooper, A., Delattre, F., Hewage, S. G., Rabani, G., Nutley, M. and Woisel, P. (2007) An investigation of the complexation of a TTF derivative with alpha-, beta- and gamma-cyclodextrins in aqueous media. Tetrahedron Letters, 48(48), pp. 8430-8433. (doi: 10.1016/j.tetlet.2007.09.167)

Abstract

This Letter, describes the complexation of of alpha-, beta- and gamma-cyclodextrins (1-3) with TTF derivative 4 in water. In particular, we show using H-1, C-13 NMR, UV-vis spectroscopy and isothermal titration calorimetry that beta-cyclodextrin 2 forms an effective complex with 4. Complex 2.4 can be conveniently disassembled upon the addition of 1-adamantanol. .

• Item Type: Articles
• Keywords: ADAMANTANECARBOXYLATE BETA-CYCLODEXTRIN BUILDING-BLOCKS C-13 COMPLEX COMPLEXES cyclodextrins GLUCOSE-OXIDASE INCLUSION COMPLEXES isothermal titration calorimetry LANGMUIR-BLODGETT-FILMS NMR POLYMER MEMBRANE pseudorotaxanes REDOX SPECTROSCOPY Supramolecular Chemistry tetrathiafulvalene TETRATHIAFULVALENE DERIVATIVES TTF UNIT WATER
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Nutley, Mrs Margaret and Cooke, Professor Graeme and Rabani, Dr Gouher and Cooper, Professor Alan
• Authors: Bria, M., Cooke, G., Cooper, A., Delattre, F., Hewage, S. G., Rabani, G., Nutley, M., and Woisel, P.
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Tetrahedron Letters
• ISSN: 0040-4039