An investigation of the complexation of a TTF derivative with alpha-, beta- and gamma-cyclodextrins in aqueous media

Bria, M., Cooke, G., Cooper, A., Delattre, F., Hewage, S. G., Rabani, G., Nutley, M. and Woisel, P. (2007) An investigation of the complexation of a TTF derivative with alpha-, beta- and gamma-cyclodextrins in aqueous media. Tetrahedron Letters, 48(48), pp. 8430-8433. (doi:10.1016/j.tetlet.2007.09.167)

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Abstract

This Letter, describes the complexation of of alpha-, beta- and gamma-cyclodextrins (1-3) with TTF derivative 4 in water. In particular, we show using H-1, C-13 NMR, UV-vis spectroscopy and isothermal titration calorimetry that beta-cyclodextrin 2 forms an effective complex with 4. Complex 2.4 can be conveniently disassembled upon the addition of 1-adamantanol. .

Item Type:Articles
Keywords:ADAMANTANECARBOXYLATE BETA-CYCLODEXTRIN BUILDING-BLOCKS C-13 COMPLEX COMPLEXES cyclodextrins GLUCOSE-OXIDASE INCLUSION COMPLEXES isothermal titration calorimetry LANGMUIR-BLODGETT-FILMS NMR POLYMER MEMBRANE pseudorotaxanes REDOX SPECTROSCOPY Supramolecular Chemistry tetrathiafulvalene TETRATHIAFULVALENE DERIVATIVES TTF UNIT WATER
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Rabani, Dr Gouher and Nutley, Mrs Margaret and Cooper, Professor Alan and Cooke, Professor Graeme
Authors: Bria, M., Cooke, G., Cooper, A., Delattre, F., Hewage, S. G., Rabani, G., Nutley, M., and Woisel, P.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Tetrahedron Letters
ISSN:0040-4039

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