C-C coupling constants, J(CC), are reliable probes for alpha-C-C agostic structures

Boulho, C., Keys, T., Coppel, Y., Vendier, L., Etienne, M., Locati, A., Bessac, F., Maseras, F., Pantazis, D. A. and McGrady, J. E. (2009) C-C coupling constants, J(CC), are reliable probes for alpha-C-C agostic structures. Organometallics, 28(4), pp. 940-943. (doi: 10.1021/om800999a)

Full text not currently available from Enlighten.

Publisher's URL: http://dx.doi.org/10.1021/om800999a

Abstract

In contrast to structural parameters extracted from X-ray diffraction experiments, CC coupling constants (J(CC)) prove to be reliable and sensitive probes of alpha-C-C agostic character.

Item Type:Articles
Keywords:BOND ACTIVATION DERIVATIVES DIFFRACTION HELP METAL ALKYL COMPLEXES METALLACYCLOBUTANES NIOBIUM COMPLEX PARAMETERS PROBES REACTIVITY REDUCTIVE ELIMINATION RHODIUM Structure X-RAY X-RAY-DIFFRACTION
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:McGrady, Prof John
Authors: Boulho, C., Keys, T., Coppel, Y., Vendier, L., Etienne, M., Locati, A., Bessac, F., Maseras, F., Pantazis, D. A., and McGrady, J. E.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Organometallics
Publisher:American Chemical Society
ISSN:0276-7333
ISSN (Online):1520-6041
Published Online:21 January 2009

University Staff: Request a correction | Enlighten Editors: Update this record

Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
427011In search of a fundamental understanding of C-H & C-C agostic bondsJohn McGradyEngineering & Physical Sciences Research Council (EPSRC)EP/C534425/1CHEM - CHEMISTRY