Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature

Yip, T.W.S., Cussen, E.J. and MacLaren, D.A. (2010) Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature. Chemical Communications, 46(5), pp. 698-700. (doi:10.1039/b920837b)

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Abstract

The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH·H2O at room temperature to give targeted compositions in the series HxLi1-xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:MacLaren, Dr Donald
Authors: Yip, T.W.S., Cussen, E.J., and MacLaren, D.A.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Physics and Astronomy
Journal Name:Chemical Communications
Journal Abbr.:Chem. Comm.
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:30 November 2009
Copyright Holders:Copyright © 2010 Royal Society of Chemistry
First Published:First published in Chemical Communications 46(5):698-700
Publisher Policy:Reproduced in accordance with the copyright policy of the publisher.

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