The thinning of lamellae in surfactant-free foams with non-Newtonian liquid phase

Brush, L.B. and Roper, S.M. (2008) The thinning of lamellae in surfactant-free foams with non-Newtonian liquid phase. Journal of Fluid Mechanics, 616, pp. 235-262. (doi:10.1017/S0022112008003790)

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Abstract

Thinning rates of liquid lamellae in surfactant-free non-Newtonian gas–liquid foams, appropriate for ceramic or polymer melts and also in metals near the melting point, are derived in two dimensions by matched asymptotic analysis valid at small capillary number. The liquid viscosity is modelled (i) as a power-law function of the shear rate and (ii) by the Ellis law. Equations governing gas–liquid interface dynamics and variations in liquid viscosity are derived within the lamellar, transition and plateau border regions of a corner of the liquid surrounding a gas bubble. The results show that the viscosity varies primarily in the very short transition region lying between the lamellar and the Plateau border regions where the shear rates can become very large. In contrast to a foam with Newtonian liquid, the matching condition which determines the rate of lamellar thinning is non-local. In all cases considered, calculated lamellar thinning rates exhibit an initial transient thinning regime, followed by a t−2 power-law thinning regime, similar to the behaviour seen in foams with Newtonian liquid phase. In semi-arid foam, in which the liquid fraction is O(1) in the small capillary number, results explicitly show that for both the power-law and Ellis-law model of viscosity, the thinning of lamella in non-Newtonian and Newtonian foams is governed by the same equation, from which scaling laws can be deduced. This result is consistent with recently published experimental results on forced foam drainage. However, in an arid foam, which has much smaller volume fraction of liquid resulting in an increase in the Plateau border radius of curvature as lamellar thinning progresses, the scaling law depends on the material and the thinning rate is not independent of the liquid viscosity model parameters. Calculations of thinning rates, viscosities, pressures, interface shapes and shear rates in the transition region are presented using data for real liquids from the literature. Although for shear-thinning fluids the power-law viscosity becomes infinite at the boundaries of the internal transition region where the shear rate is zero, the interface shape, the pressure and the internal shear rates calculated by both rheological models are indistinguishable.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Roper, Dr Steven
Authors: Brush, L.B., and Roper, S.M.
Subjects:Q Science > QC Physics
College/School:College of Science and Engineering > School of Mathematics and Statistics > Mathematics
Journal Name:Journal of Fluid Mechanics
Journal Abbr.:J. Fluid Mech.
Publisher:Cambridge University Press
ISSN:0022-1120
ISSN (Online):1469-7645
Published Online:14 November 2008
Copyright Holders:Copyright © 2008 Cambridge University Press
First Published:First published in Journal of Fluid Mechanics 616:235-262
Publisher Policy:Reproduced in accordance with the copyright policy of the publisher.

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