Exploiting and controlling gel-to-crystal transitions in multicomponent supramolecular gels

Giuri, D., Marshall, L., Dietrich, B. , McDowall, D., Thomson, L., Newton, J. Y., Wilson, C. , Schweins, R. and Adams, D. J. (2021) Exploiting and controlling gel-to-crystal transitions in multicomponent supramolecular gels. Chemical Science, 12(28), pp. 9720-9725. (doi: 10.1039/D1SC02347K) (PMID:34349943) (PMCID:PMC8293982)

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Abstract

Multicomponent supramolecular gels provide opportunities to form materials that are not accessible when using the single components alone. Different scenarios are possible when mixing multiple components, from complete co-assembly (mixing of the components within the self-assembled structures formed) to complete self-sorting such that each structure contains only one of the components. Most examples of multicomponent gels that currently exist form stable gels. Here, we show that this can be used to control the mechanical properties of the gels, but what is probably most exciting is that we show that we can use a magnetic field to control the shape of the crystals. The gelling component aligns in a magnetic field and so results in anisotropic crystals being formed.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Dietrich, Bart and Thomson, Miss Lisa and Adams, Dave and Marshall, Miss Libby and McDowall, Mr Daniel and Wilson, Dr Claire and Giuri, Demetra
Creator Roles:
Giuri, D.Conceptualization, Data curation, Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review and editing
Marshall, L.Data curation, Investigation, Methodology, Writing – original draft, Writing – review and editing
Dietrich, B.Data curation, Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review and editing
McDowall, D.Data curation, Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review and editing
Thomson, L.Data curation, Investigation, Methodology, Writing – original draft, Writing – review and editing
Wilson, C.Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review and editing
Adams, D.Conceptualization, Formal analysis, Funding acquisition, Investigation, Methodology, Supervision, Project administration, Writing – original draft, Writing – review and editing
Authors: Giuri, D., Marshall, L., Dietrich, B., McDowall, D., Thomson, L., Newton, J. Y., Wilson, C., Schweins, R., and Adams, D. J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Science
Publisher:Royal Society of Chemistry
ISSN:2041-6520
ISSN (Online):2041-6520
Published Online:14 June 2021
Copyright Holders:Copyright © 2021 The Authors
First Published:First published in Chemical Science 12(28): 9720-9725
Publisher Policy:Reproduced under a Creative Commons Licence

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
305912Spatially- and temporally-controlled photothermal GelsDave AdamsLeverhulme Trust (LEVERHUL)RPG-2019-165Chemistry
303747Digital-Chemical-Robotics for Translation of Code to Molecules and Complex Chemical SystemsLeroy CroninEngineering and Physical Sciences Research Council (EPSRC)EP/S019472/1Chemistry
300445Gel-based Photoelectrodes for Clean FuelsDave AdamsLeverhulme Trust (LEVERHUL)RPG-2018-013Chemistry