Zachariou, A., Hawkins, A. P. , Suwardiyanto, A., Collier, P., Barrow, N., Howe, R., Parker, S. F. and Lennon, D. (2021) New spectroscopic insight into the deactivation of a ZSM‐5 methanol‐to‐hydrocarbons catalyst. ChemCatChem, 13(11), pp. 2625-2633. (doi: 10.1002/cctc.202100286)
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Abstract
The nature of the hydrocarbon pool at different stages of the methanol-to-hydrocarbons reaction over ZSM-5 is examined. A combination of reaction testing, analytical and spectroscopic techniques is employed to investigate changes in the nature and form of the hydrocarbon pool as a function of reaction conditions and reaction time. It is shown that inelastic neutron scattering spectroscopy (INS) complements other spectroscopic methods for observing molecular components in the hydrocarbon pool of working catalysts. INS is uniquely able to spectroscopically identify the form of coke species present in deactivated catalysts.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Zachariou, Miss Andrea and Parker, Dr Stewart and Lennon, Professor David and Hawkins, Alexander |
| Authors: | Zachariou, A., Hawkins, A. P., Suwardiyanto, A., Collier, P., Barrow, N., Howe, R., Parker, S. F., and Lennon, D. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | ChemCatChem |
| Publisher: | Wiley |
| ISSN: | 1867-3880 |
| ISSN (Online): | 1867-3899 |
| Published Online: | 08 March 2021 |
| Copyright Holders: | Copyright © 2021 The Authors |
| First Published: | First published in ChemCatChem 13(11): 2625-2633 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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