Haydeeite: a spin-1/2 kagome ferromagnet

Boldrin, D. , Fåk, B., Enderle, M., Bieri, S., Ollivier, J., Rols, S., Manuel, P. and Wills, A.S. (2015) Haydeeite: a spin-1/2 kagome ferromagnet. Physical Review B, 91(22), 220408(R). (doi: 10.1103/PhysRevB.91.220408)

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Abstract

The mineral haydeeite, α -MgCu 3 ( OD ) 6 Cl 2 , is a S = 1 2 kagome ferromagnet that displays long-range magnetic order below T C = 4.2 K with a strongly reduced moment. Our inelastic neutron scattering data show clear spin-wave excitations that are well described by a Heisenberg Hamiltonian with a ferromagnetic nearest-neighbor exchange J 1 = − 38 K and an antiferromagnetic exchange J d = + 11 K across the hexagons of the kagome lattice. These values place haydeeite in the ferromagnetic part of the phase diagram, close to the cuboc2 type noncoplanar 12-sublattice antiferromagnetic order of cuboctahedral symmetry. Diffuse dynamic short-range ferromagnetic correlations observed above T C persist well into the ferromagnetically ordered phase with a behavior distinct from critical scattering.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Boldrin, Dr David
Authors: Boldrin, D., Fåk, B., Enderle, M., Bieri, S., Ollivier, J., Rols, S., Manuel, P., and Wills, A.S.
College/School:College of Science and Engineering > School of Physics and Astronomy
Journal Name:Physical Review B
Publisher:American Physical Society
ISSN:1098-0121
ISSN (Online):1550-235X
Published Online:23 June 2015

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