Low, K.-H., Li, C.-H., Roy, V. A.L. , Chui, S. S.-Y., Lai-Fung Chan, S. and Che, C.-M. (2010) Homoleptic copper(I) phenylselenolate polymer as a single-source precursor for Cu2Se nanocrystals. Structure, photoluminescence and application in field-effect transistor. Chemical Science, 1(4), pp. 515-518. (doi: 10.1039/c0sc00212g)
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Abstract
We present the one-dimensional polymeric structures of [Cu(SePh)]∞1 and [Cu(SeMe)]∞2 that were solved by using powder X-ray diffraction data. Using a field-effect transistor (FET) set-up, the hole mobility of complex 1 was found to be 4 × 10−2 cm2 V−1 s−1, comparable to that of regioregular poly(3-hexylthiophene) (P3HT). Phase-pure orthorhombic and cubic Cu2Se were synthesized from 1 as a single precursor under vacuum and inert atmosphere, respectively.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Vellaisamy, Professor Roy |
Authors: | Low, K.-H., Li, C.-H., Roy, V. A.L., Chui, S. S.-Y., Lai-Fung Chan, S., and Che, C.-M. |
College/School: | College of Science and Engineering > School of Engineering |
Journal Name: | Chemical Science |
Publisher: | Royal Society of Chemistry |
ISSN: | 2041-6520 |
ISSN (Online): | 2041-6539 |
Published Online: | 29 June 2010 |
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