Hydrophilic poly-ether side-chained benzodithiophene-based homopolymer for solar cells and field-effect transistors

Liu, Q., Bao, X., Yan, Y., Du, Z., Roy, V.A.L. , Zhu, D., Sun, M., Lee, C.S. and Yang, R. (2014) Hydrophilic poly-ether side-chained benzodithiophene-based homopolymer for solar cells and field-effect transistors. Journal of Materials Science, 50(5), pp. 2263-2271. (doi: 10.1007/s10853-014-8789-8)

Abstract

Two benzodithiophene (BDT)-based homopolymers which have different mole ratios of poly-ether side chain substitute were synthesized by Stille coupling reaction. The polymers show decomposition temperature (T d) around 317 °C and optical band gap around 2.2 eV. Solar cell devices with bulk heterojunction structure and field-effect transistors devices were fabricated to evaluate the photovoltaic properties of resultant polymers. Solar cell devices based on the polymer with 100 % poly-ether side chain (P1) show low power conversion efficiencies (PCEs) of 0.71 % resulting from the poor morphology of active layer which has rough surface and fairly large domain size due to the high aggregation tendency of P1:PCBM ([6,6]-phenyl-C61-butyric acid methyl ester) blend thin film as active layer in the structure of devices. Polymer with alternating poly-ether and alkoxy chained BDT (P2) and PCBM blend film shows smooth surface and appropriate domain size, which help to enhance the hole transportation and photovoltaic performances. The PCEs of the devices based on P2 reached 2.00 % which is a decent result for BDT-based homopolymer donor with relatively large band gap (ca. 2.2 eV). These two polymers exhibited mobilities of 3.95 × 10−4 and 6.18 × 10−4 cm2/Vs in field-effect transistors, respectively.

• Item Type: Articles
• Additional Information: The authors are deeply grateful to the National Natural Science Foundation of China (Project Nos. 21274134, 51173199, 61107090), New Century Excellent Talents in University (NCET-11-0473), Shandong Provincial Natural Science Foundation (ZR2011BZ007), Qingdao Municipal Science and Technology Program (11-2-4-22-hz, 13-1-4-200-jch) and Shenzhen Municipal Science and Technology Program (JCYJ20130401145617279) for financial support.
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Vellaisamy, Professor Roy
• Authors: Liu, Q., Bao, X., Yan, Y., Du, Z., Roy, V.A.L., Zhu, D., Sun, M., Lee, C.S., and Yang, R.
• College/School: College of Science and Engineering > School of Engineering > Electronics and Nanoscale Engineering
• Journal Name: Journal of Materials Science
• Publisher: Springer
• ISSN: 0022-2461
• ISSN (Online): 1573-4803
• Published Online: 24 December 2014