A comparison of 2,7-dihydro-2,2,7,7-tetramethyl-3,6-diphenyl- 1,4,5-thia-diazepine and the corresponding 1,1-dioxide

Cuthbertson, E., Frampton, C.S. and MacNicol, D.D. (2001) A comparison of 2,7-dihydro-2,2,7,7-tetramethyl-3,6-diphenyl- 1,4,5-thia-diazepine and the corresponding 1,1-dioxide. Acta Crystallographica. Section C: Crystal Structure Communications, 57(4), pp. 431-432. (doi: 10.1107/S0108270100020564)

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Publisher's URL: http://dx.doi.org/10.1107/S0108270100020564

Abstract

The structures of the highly substituted title heterocycles, C20H22N2S and C20H22N2O2S, have been determined at 123 (1) K. Both molecules possess exact C-2 symmetry and the seven- membered rings have very similar twist-boat conformations. The magnitudes of the C-S-C bond angles, 107.13 (6) and 108.27 (7)degrees, respectively, are influenced significantly by the four substituent methyl groups on the seven-membered rings.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:MacNicol, Dr David
Authors: Cuthbertson, E., Frampton, C.S., and MacNicol, D.D.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Acta Crystallographica. Section C: Crystal Structure Communications
Publisher:Wiley-Blackwell Publishing, Inc.
ISSN:0108-2701
ISSN (Online):1600-5759

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