Blake, A.J., Felloni, M., Hubberstey, P., Schröder, M. and Wilson, C. (2001) Hexakis(dimethyl sulfoxide)nickel(II) dinitrate dimethyl sulfoxide disolvate. Acta Crystallographica. Section E: Structure Reports Online, 57(12), m556-m557. (doi: 10.1107/s1600536801016403)
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Abstract
The title compound, [Ni(C2H6OS)6](NO3)2·2C2H6OS, comprises centrosymmetric [Ni(dmso)6]2+ cations, nitrate anions and non-coordinated dimethyl sulfoxide solvent molecules. The octahedral geometry of the cation is very regular, with Ni-O interatomic distances and O-Ni-O interatomic angles falling within narrow ranges 2.0485 (9)-2.0665 (9) Å and 89.12 (4)-93.27 (4)°, respectively. Two weak C-H...O hydrogen-bonding contacts link cations and anions to form a chain which lies along the [111] direction.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
| Authors: | Blake, A.J., Felloni, M., Hubberstey, P., Schröder, M., and Wilson, C. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Acta Crystallographica. Section E: Structure Reports Online |
| Publisher: | International Union of Crystallography |
| ISSN: | 1600-5368 |
| Published Online: | 10 October 2001 |
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