Carbonyl[hydrotris(3,5-dimethylpyrazol-1-yl)borato]copper(I) acetonitrile solvate

Blake, A. J., Carling, D. A., George, M. W., Hubberstey, P., Lopez Garcia, R. and Wilson, C. (2002) Carbonyl[hydrotris(3,5-dimethylpyrazol-1-yl)borato]copper(I) acetonitrile solvate. Acta Crystallographica. Section E: Structure Reports Online, E58, m41-m42. (doi: 10.1107/s1600536801021730)

Abstract

The title compound, [Cu(C15H22BN6)(CO)]·C2H3N, crystallizes as neutral [Tp*Cu(CO)] {[Tp*]- = hydro­tris(3,5-di­methyl­pyrazol-1-yl)­borate} molecular units and non-coordinated aceto­nitrile mol­ecules. The distorted tetrahedral coordination geometry of the copper(I) centre comprises the three N atoms of the [Tp*]- anion [Cu-N 2.033 (2)-2.054 (2) Å] and the C atom of the carbon monoxide mol­ecule [Cu-C 1.785 (4) Å].

• Item Type: Articles
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Wilson, Dr Claire
• Authors: Blake, A. J., Carling, D. A., George, M. W., Hubberstey, P., Lopez Garcia, R., and Wilson, C.
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Acta Crystallographica. Section E: Structure Reports Online
• Publisher: International Union of Crystallography
• ISSN: 1600-5368
• ISSN (Online): 1600-5368
• Published Online: 11 January 2002
• Copyright Holders: Copyright © 2002 International Union of Crystallography
• First Published: First published in Acta Cryst Section E: Structure Reports Online E58:m41-m42
• Publisher Policy: Reproduced under License