Mechanistic insight into the lanthanide (iii) salt catalysed monoacylation of symmetrical diols from structural models

Clarke, P. A., Arnold, P. L., Smith, M. A., Natrajan, L. S., Wilson, C. and Chan, C. (2003) Mechanistic insight into the lanthanide (iii) salt catalysed monoacylation of symmetrical diols from structural models. Chemical Communications, 2003(20), pp. 2588-2589. (doi: 10.1039/B308171K) (PMID:14594294)

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Abstract

Model studies are presented that suggest the mechanism of the lanthanide(III) salt catalysed mono acylation of symmetrical diols proceeds via chelation of the diol and the anhydride to the lanthanide salt, followed by an ‘intramolecular’ acyl transfer.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Clarke, P. A., Arnold, P. L., Smith, M. A., Natrajan, L. S., Wilson, C., and Chan, C.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:15 September 2003

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