Formation of [(L)Ni(μ 2 -S)x{Fe(CO) 3 }x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase

Stenson, P. A., Marin-Becerra, A., Wilson, C. , Blake, A. J., McMaster, J. and Schröder, M. (2006) Formation of [(L)Ni(μ 2 -S)x{Fe(CO) 3 }x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase. Chemical Communications, 2006(3), pp. 317-319. (doi: 10.1039/B509798C) (PMID:16391746)

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Abstract

The binuclear [Ni(L)Fe(CO)3], 1, and trinuclear [Ni(L){Fe(CO)3}2], 2, complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via μ2-S bridging modes, C[double bond, length as m-dash]N imine π-bonds and potential Ni–Fe bonding interactions.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Stenson, P. A., Marin-Becerra, A., Wilson, C., Blake, A. J., McMaster, J., and Schröder, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:24 November 2005

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