Selective oxo functionalization of the uranyl ion with 3d metal cations

Arnold, P. L., Patel, D., Blake, A. J., Wilson, C. and Love, J. B. (2006) Selective oxo functionalization of the uranyl ion with 3d metal cations. Journal of the American Chemical Society, 128(30), pp. 9610-9611. (doi: 10.1021/ja0634167) (PMID:16866497)

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Abstract

The linear uranyl dication [UO2]2+ can be bound in one of two coordination sites in the ditopic Pacman-shaped pyrrolic macrocyle H4L. Incorporation of Mn2+, Fe2+, or Co2+ cations in the second donor compartment affords the first uranyl complexes with a transition-metal-functionalized oxo group.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Arnold, P. L., Patel, D., Blake, A. J., Wilson, C., and Love, J. B.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of the American Chemical Society
Publisher:American Chemical Society
ISSN:0002-7863
ISSN (Online):1520-5126
Published Online:12 July 2006

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