Modelling and computation of curing and damage of thermosets

Mergheim, J., Possart, G. and Steinmann, P. (2012) Modelling and computation of curing and damage of thermosets. Computational Materials Science, 53(1), p. 359. (doi: 10.1016/j.commatsci.2011.09.013)

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Abstract

The curing of thermosets is a complex process involving the transition from a fluid into a (visco-) elastic solid. This phase transition comes along with an increase in stiffness and a volume shrinkage of the polymer. The latter may lead to severe residual strains and stresses, which in turn can cause damage in the final, usually quasi-brittle material. In this contribution a constitutive model is developed which takes into account the curing of a thermosetting material together with the process-induced damage as resulting from curing shrinkage. The curing of the material is governed by a phenomenological hypoelastic constitutive equation which includes temporal evolutions for stiffness and volume shrinkage. Thermal and viscous effects are neglected in the present study. An isotropic gradient-enhanced damage model is adapted to describe the damage evolution. The curing-damage model is implemented into a finite element code and numerical examples for thermosetting materials demonstrate that the proposed model is capable to predict cure-induced damage in thermosets.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Steinmann, Professor Paul
Authors: Mergheim, J., Possart, G., and Steinmann, P.
College/School:College of Science and Engineering > School of Engineering > Infrastructure and Environment
Journal Name:Computational Materials Science
Publisher:Elsevier
ISSN:0927-0256
ISSN (Online):1879-0801
Published Online:22 October 2011
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