Schmidt, B. V.K.J. , Hetzer, M., Ritter, H. and Barner-Kowollik, C. (2012) Miktoarm star polymers via cyclodextrin-driven supramolecular self-assembly. Polymer Chemistry, 3(11), pp. 3064-3067. (doi: 10.1039/c2py20214j)
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Abstract
We report the formation of a novel class of supramolecular miktoarm star polymers via cyclodextrin host–guest chemistry. Reversible addition–fragmentation chain transfer polymerization from difunctional guest- or alkyne-containing chain transfer agents and copper(I)-catalyzed azide–alkyne cycloaddition leads to host- and guest-containing acrylamido polymers, namely poly(N,N-dimethylacrylamide) and poly(N,N-diethylacrylamide). Subsequently, a supramolecular miktoarm star polymer was formed and characterized via dynamic light scattering and rotating frame nuclear Overhauser effect spectroscopy.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Schmidt, Dr Bernhard |
Authors: | Schmidt, B. V.K.J., Hetzer, M., Ritter, H., and Barner-Kowollik, C. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Polymer Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 1759-9954 |
ISSN (Online): | 1759-9962 |
Published Online: | 13 June 2012 |
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