Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks

Hwang, J., Lee, H.-C., Antonietti, M. and Schmidt, B. V.K.J. (2017) Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks. Polymer Chemistry, 8(40), pp. 6204-6208. (doi:10.1039/C7PY01607G)

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Abstract

Free radical and RAFT polymerization of vinyl esters with different molecular dimensions are conducted in the nanochannels of metal–organic-frameworks (MOFs). The combination of MOFs with the RAFT technique enables the synthesis of highly isotactic poly(vinyl ester)s with a controlled molecular weight and narrow molecular weight distribution, and stereocontrolled isotactic-block-atactic vinyl ester block copolymers.

Item Type:Articles
Additional Information:J. H. acknowledges Max Planck Society for a Postdoc scholarship. Open Access funding provided by the Max Planck Society.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Schmidt, Dr Bernhard
Authors: Hwang, J., Lee, H.-C., Antonietti, M., and Schmidt, B. V.K.J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Polymer Chemistry
Publisher:Royal Society of Chemistry
ISSN:1759-9954
ISSN (Online):1759-9962
Published Online:29 September 2017
Copyright Holders:Copyright © 2017 The Royal Society of Chemistry
First Published:First published in Polymer Chemistry 8(40): 6204-6208
Publisher Policy:Reproduced under a Creative Commons License

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