Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection

Janusson, E. , de Kler, N., Vilà-Nadal, L. , Long, D.-L. and Cronin, L. (2019) Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection. Chemical Communications, 55(41), pp. 5797-5800. (doi:10.1039/C9CC02361E) (PMID:31041957)

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Abstract

By using sugars as the reducing agents, we demonstrate that it is possible to control the self-assembly of polyoxomolybdates through selective preparation of a single heteropolyanion isomer. D-(−)-Fructose has been proved to be an effective reducing sugar compared to the chemically similar carbohydrate D-(+)-glucose. The gentle reduction results in favourable formation of the Wells–Dawson type gamma isomer in 6-fold reduced form at room temperature.

Item Type:Articles
Additional Information:A correction to this article is available at http://dx.doi.org/10.1039/C9CC90217A.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Vila-Nadal, Dr Laia and Janusson, Dr Eric and de Kler, Noel and Long, Dr Deliang and Cronin, Professor Lee
Authors: Janusson, E., de Kler, N., Vilà-Nadal, L., Long, D.-L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:26 April 2019
Copyright Holders:Copyright © 2019 The Royal Society of Chemistry
First Published:First published in Chemical Communications 55:5797-5800
Publisher Policy:Reproduced under a Creative Commons License
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