Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets

Canaj, A. B. , Singh, M. K., Marti, E. R., Damjanović, M., Wilson, C. , Céspedes, O., Wernsdorfer, W., Rajaraman, G. and Murrie, M. (2019) Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets. Chemical Communications, (doi:10.1039/C9CC00965E) (PMID:31049540) (Early Online Publication)

Canaj, A. B. , Singh, M. K., Marti, E. R., Damjanović, M., Wilson, C. , Céspedes, O., Wernsdorfer, W., Rajaraman, G. and Murrie, M. (2019) Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets. Chemical Communications, (doi:10.1039/C9CC00965E) (PMID:31049540) (Early Online Publication)

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Abstract

A new nine-coordinate, air-stable Dy(III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate Ucal barriers of over 600 K.

Item Type:Articles
Additional Information:G. R. thanks the SERB (EMR/2014/00024) for funding. MKS thanks IIT Bombay for a fellowship.
Status:Early Online Publication
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire and Tsanai, Mr Angelos and Murrie, Professor Mark
Authors: Canaj, A. B., Singh, M. K., Marti, E. R., Damjanović, M., Wilson, C., Céspedes, O., Wernsdorfer, W., Rajaraman, G., and Murrie, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:29 April 2019
Copyright Holders:Copyright © 2019 The Authors
First Published:First published in Chemical Communications 2019
Publisher Policy:Reproduced under a Creative Commons License
Data DOI:10.5525/gla.researchdata.789

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
696981Putting the Squeeze on Molecule-Based MagnetsMark MurrieEngineering and Physical Sciences Research Council (EPSRC)EP/N01331X/1CHEM - CHEMISTRY