Daisley, A. and Hargreaves, J. S.J. (2019) The role of interstitial species upon the ammonia synthesis activity of ternary Fe-Mo-C(N) and Ni-Mo-C(N) phases. Journal of Energy Chemistry, 39, pp. 170-175. (doi: 10.1016/j.jechem.2019.01.026)
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Abstract
Fe3Mo3C has been prepared and its activity for ammonia synthesis was evaluated. As had been observed previously for Co3Mo3C, it was found to be inactive at 400 °C. At 500 °C activity developed and this can be related to the substitution of lattice carbon by nitrogen. Application of a simple topotactic route to prepare Ni2Mo3C from Ni2Mo3N proved unsuccessful, with the resultant carbonitride formed under optimal synthesis conditions being active for ammonia synthesis at 400 °C.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Daisley, Miss Angela and Hargreaves, Professor Justin |
| Authors: | Daisley, A., and Hargreaves, J. S.J. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of Energy Chemistry |
| Publisher: | Elsevier |
| ISSN: | 2095-4956 |
| ISSN (Online): | 2095-4956 |
| Published Online: | 04 February 2019 |
| Copyright Holders: | Copyright © 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences |
| First Published: | First published in Journal of Energy Chemistry 39:170-175 |
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