Comment on “Stabilization of low-valent iron(I) in a high-valent vanadium(V) oxide cluster”

Sproules, S. (2019) Comment on “Stabilization of low-valent iron(I) in a high-valent vanadium(V) oxide cluster”. Angewandte Chemie (International Edition), 58(30), pp. 10043-10047. (doi:10.1002/anie.201811125) (PMID:31267608)

[img] Text
173921.pdf - Accepted Version
Restricted to Repository staff only until 3 July 2020.

871kB
[img] Text
173921Supp.pdf - Supplemental Material
Restricted to Repository staff only until 3 July 2020.

1MB

Abstract

A recent Communication in this journal reported the stabilization of low‐valent iron(I) in a fully oxidized polyoxovanadate. With no ligand‐field argument to support such an assignment, a re‐evaluation of the data accompanied by detailed computational analysis reveals the redox chemistry is localized to the polyoxovanadate, and when reduced, instigates a spin transition at iron.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Sproules, Dr Stephen
Authors: Sproules, S.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Publisher:Wiley
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:03 July 2019
Copyright Holders:Copyright © 2019 Wiley-VCH Verlag GmbH and Co. KGaA
First Published:First published in Angewandte Chemie (International Edition) 58(30): 10043-10047
Publisher Policy:Reproduced in accordance with the publisher copyright policy

University Staff: Request a correction | Enlighten Editors: Update this record