Lin, C.-G., Zhou, W., Xiong, X.-T., Xuan, W., Kitson, P. J., Long, D.-L. , Chen, W., Song, Y.-F. and Cronin, L. (2018) Digital control of multistep hydrothermal synthesis by using 3D printed reactionware for the synthesis of metal–organic frameworks. Angewandte Chemie (International Edition), 57(51), pp. 16716-16720. (doi: 10.1002/anie.201810095) (PMID:30370977) (PMCID:PMC6391986)
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Abstract
Hydrothermal‐synthesis‐based reactions are normally single step owing to the difficulty of manipulating reaction mixtures at high temperatures and pressures. Herein we demonstrate a simple, cheap, and modular approach to the design reactors consisting of partitioned chambers, to achieve multi‐step synthesis under hydrothermal conditions, in digitally defined reactionware produced by 3D printing. This approach increases the number of steps that can be performed sequentially and allows an increase in the options available for the control of hydrothermal reactions. The synthetic outcomes of the multi‐stage reactions can be explored by varying reaction compositions, number of reagents, reaction steps, and reaction times, and these can be tagged to the digital blueprint. To demonstrate the potential of this approach a series of polyoxometalate (POM)‐containing metal–organic frameworks (MOFs) unavailable by “one‐pot” methods were prepared as well as a set of new MOFs.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Xuan, Mr Weimin and Kitson, Dr Philip and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Lin, C.-G., Zhou, W., Xiong, X.-T., Xuan, W., Kitson, P. J., Long, D.-L., Chen, W., Song, Y.-F., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Angewandte Chemie (International Edition) |
Publisher: | Wiley |
ISSN: | 1433-7851 |
ISSN (Online): | 1521-3773 |
Published Online: | 29 October 2018 |
Copyright Holders: | Copyright © 2018 The Authors |
First Published: | First published in Angewandte Chemie (International Edition) 57(51):16716-16720 |
Publisher Policy: | Reproduced under a Creative Commons License |
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